Could not find a part of the path 'C:\Users\user\Documents\OpenRPA\extensions'

That error is related to nuget, not python.

OpenRPA uses an embedded version of python by default, so packages must be installed using the pip install activity or from inside the local python folder.
See here as well

Check the logs for any errors if using the activity, or run pip install from command line as explained in the link and see if you get any errors that can help.

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